In contrast to the phase-space formulation, the Schrödinger picture uses the position or momentum representations (see also ).
position and momentum space
The chief advantage of the phase-space formulation is that it makes quantum mechanics appear as similar to Hamiltonian mechanics as possible by avoiding the operator formalism, thereby "'freeing' the quantization of the 'burden' of the Hilbert space".5 This formulation is statistical in nature and offers logical connections between quantum mechanics and classical statistical mechanics, enabling a natural comparison between the two (see classical limit). Quantum mechanics in phase space is often favored in certain quantum optics applications (see optical phase space), or in the study of decoherence and a range of specialized technical problems, though otherwise the formalism is less commonly employed in practical situations.6
The phase space formulation can be applied to scattering theory.7 It plays a crucial role in establishing the idea of S-symplectomorphism as a precise classical counterpart of S-matrix.
The conceptual ideas underlying the development of quantum mechanics in phase space have branched into mathematical offshoots such as Kontsevich's deformation-quantization (see Kontsevich quantization formula) and noncommutative geometry.
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The energy eigenstate distributions are known as stargenstates, ★-genstates, stargenfunctions, or ★-genfunctions, and the associated energies are known as stargenvalues or ★-genvalues.
The energy eigenstate distributions are known as stargenstates, ★-genstates, stargenfunctions, or ★-genfunctions, and the associated energies are known as stargenvalues or ★-genvalues.
Terms the article defines in bold, quoted in context.
Categories:
Hamiltonian mechanics
Symplectic geometry
Mathematical quantization
Foundational quantum physics
1,634 words · 25 references · revision 1383637993 · CC BY-SA 4.0
The phase-space distribution f(x, p) of a quantum state is a quasiprobability distribution. In the phase-space formulation, the phase-space distribution may be treated as the fundamental, primitive description of the quantum system, without any reference to wave functions or density matrices.8
There are several different ways to represent the distribution, all interrelated.910 The most noteworthy is the Wigner representation, W(x, p), discovered first.4 Other representations (in approximately descending order of prevalence in the literature) include the Glauber–Sudarshan P,1112Husimi Q,13 Kirkwood–Rihaczek, Mehta, Rivier, and Born–Jordan representations.1415 These alternatives are most useful when the Hamiltonian takes a particular form, such as normal order for the Glauber–Sudarshan P-representation. Since the Wigner representation is the most common, this article will usually stick to it, unless otherwise specified.
The phase-space distribution possesses properties akin to the probability density in a 2n-dimensional phase space. For example, it is real-valued, unlike the generally complex-valued wave function. We can understand the probability of lying within a position interval, for example, by integrating the Wigner function over all momenta and over the position interval:
If Â(x, p) is an operator representing an observable, it may be mapped to phase space as A(x, p) through the Wigner transform. Conversely, this operator may be recovered by the Weyl transform.
The expectation value of the observable with respect to the phase-space distribution is216
Regions of such negative value are provable to be "small": they cannot extend to compact regions larger than a few ħ, and hence disappear in the classical limit. They are shielded by the uncertainty principle, which does not allow precise localization within phase-space regions smaller than ħ, and thus renders such "negative probabilities" less paradoxical. If the left side of the equation is to be interpreted as an expectation value in the Hilbert space with respect to an operator, then in the context of quantum optics this equation is known as the optical equivalence theorem. (For details on the properties and interpretation of the Wigner function, see its main article.)
An alternative phase-space approach to quantum mechanics seeks to define a wave function (not just a quasiprobability density) on phase space, typically by means of the Segal–Bargmann transform. To be compatible with the uncertainty principle, the phase-space wave function cannot be an arbitrary function, or else it could be localized into an arbitrarily small region of phase space. Rather, the Segal–Bargmann transform is a holomorphic function of . There is a quasiprobability density associated to the phase-space wave function; it is the Husimi Q representation of the position wave function.
The fundamental noncommutative binary operator in the phase-space formulation that replaces the standard operator multiplication is the star product, represented by the symbol ★.1 Each representation of the phase-space distribution has a different characteristic star product. For concreteness, we restrict this discussion to the star product relevant to the Wigner–Weyl representation.
For notational convenience, we introduce the notion of left and right derivatives. For a pair of functions f and g, the left and right derivatives are defined as
where the argument of the exponential function can be interpreted as a power series. Additional differential relations allow this to be written in terms of a change in the arguments of f and g:
It is also possible to define the ★-product in a convolution integral form,17 essentially through the Fourier transform:
The energy eigenstate distributions are known as stargenstates, ★-genstates, stargenfunctions, or ★-, and the associated energies are known as or -. These are solved, analogously to the time-independent , by the -genvalue equation,
In any representation of the phase space distribution with its associated star product, this is
or, for the Wigner function in particular,
where {{ , }} is the Moyal bracket, the Wigner transform of the quantum commutator, while { , } is the classical Poisson bracket.2
This yields a concise illustration of the correspondence principle: this equation manifestly reduces to the classical Liouville equation in the limit ħ → 0. In the quantum extension of the flow, however, the density of points in phase space is not conserved; the probability fluid appears "diffusive" and compressible.2 The concept of quantum trajectory is therefore a delicate issue here.21 See the movie for the Morse potential, below, to appreciate the nonlocality of quantum phase flow.
N.B. Given the restrictions placed by the uncertainty principle on localization, vigorously denied the physical existence of such trajectories on the microscopic scale. By means of formal phase-space trajectories, the time evolution problem of the Wigner function can be rigorously solved using the path-integral method and the , although there are severe practical obstacles in both cases.
Wigner function for number states a) n = 0, b) n = 1, and c) n = 19. Marginal distributions for x and p are recovered by integrating over p and x respectively.
The Hamiltonian for the simple harmonic oscillator in one spatial dimension in the Wigner–Weyl representation is
The ★-genvalue equation for the static Wigner function then reads
Time evolution of combined ground and 1st excited state Wigner function for the simple harmonic oscillator. Note the rigid motion in phase space corresponding to the conventional oscillations in coordinate space.
Wigner function for the harmonic oscillator ground state, displaced from the origin of phase space, i.e., a . Note the rigid rotation, identical to classical motion: this is a special feature of the SHO, illustrating the . From the general pedagogy web-site.
Consider, first, the imaginary part of the ★-genvalue equation,
This implies that one may write the ★-genstates as functions of a single argument:
With this change of variables, it is possible to write the real part of the ★-genvalue equation in the form of a modified Laguerre equation (not Hermite's equation!), the solution of which involves the Laguerre polynomials as19
introduced by Groenewold,1 with associated ★-genvalues
For the harmonic oscillator, the time evolution of an arbitrary Wigner distribution is simple. An initial W(x, p; t = 0) = F(u) evolves by the above evolution equation driven by the oscillator Hamiltonian given, by simply rigidly rotating in phase space,1
The Wigner function of a simple harmonic oscillator at different levels of excitations. The are rescaled by in order to show that the Wigner function oscillates within that radius, and decays rapidly outside of that radius.
Typically, a "bump" (or coherent state) of energy E ≫ ħω can represent a macroscopic quantity and appear like a classical object rotating uniformly in phase space, a plain mechanical oscillator (see the animated figures). Integrating over all phases (starting positions at t = 0) of such objects, a continuous "palisade", yields a time-independent configuration similar to the above static ★-genstates F(u), an intuitive visualization of the classical limit for large-action systems.6
The eigenfunctions can also be characterized by being rotationally symmetric (thus time-invariant) pure states. That is, they are functions of form that satisfy .
Free particle angular momentum
Suppose a particle is initially in a minimally uncertain Gaussian state, with the expectation values of position and momentum both centered at the origin in phase space. The Wigner function for such a state propagating freely is
where α is a parameter describing the initial width of the Gaussian, and τ = m/α2ħ.
Initially, the position and momenta are uncorrelated. Thus, in 3 dimensions, we expect the position and momentum vectors to be twice as likely to be perpendicular to each other as parallel.
However, the position and momentum become increasingly correlated as the state evolves, because portions of the distribution farther from the origin in position require a larger momentum to be reached: asymptotically,
(This relative "squeezing" reflects the spreading of the free wave packet in coordinate space.)
Indeed, it is possible to show that the kinetic energy of the particle becomes asymptotically radial only, in agreement with the standard quantum-mechanical notion of the ground-state nonzero angular momentum specifying orientation independence:25
Morse potential
The Morse potential is used to approximate the vibrational structure of a diatomic molecule.
Quantum tunneling
Tunneling is a hallmark quantum effect where a quantum particle, not having sufficient energy to fly above, still goes through a barrier. This effect does not exist in classical mechanics.
Quartic potential
Schrödinger cat state
Wigner function of two interfering coherent states evolving through the SHO Hamiltonian. The corresponding momentum and coordinate projections are plotted to the right and under the phase space plot.
10Agarwal, G. S.; Wolf, E. (1970). "Calculus for Functions of Noncommuting Operators and General Phase-Space Methods in Quantum Mechanics. II. Quantum Mechanics in Phase Space". Physical Review D. 2 (10): 2187–2205. Bibcode:1970PhRvD...2.2187A. doi:10.1103/PhysRevD.2.2187.
11Sudarshan, E. C. G. (1963). "Equivalence of Semiclassical and Quantum Mechanical Descriptions of Statistical Light Beams". Physical Review Letters. 10 (7): 277–279. Bibcode:1963PhRvL..10..277S. doi:10.1103/PhysRevLett.10.277.
13Kôdi Husimi (1940). "Some Formal Properties of the Density Matrix", Proc. Phys. Math. Soc. Jpn.22: 264–314.
14Agarwal, G. S.; Wolf, E. (1970). "Calculus for Functions of Noncommuting Operators and General Phase-Space Methods in Quantum Mechanics. I. Mapping Theorems and Ordering of Functions of Noncommuting Operators". Physical Review D. 2 (10): 2161–2186. Bibcode:1970PhRvD...2.2161A. doi:10.1103/PhysRevD.2.2161.
16Lax, Melvin (1968). "Quantum Noise. XI. Multitime Correspondence between Quantum and Classical Stochastic Processes". Physical Review. 172 (2): 350–361. Bibcode:1968PhRv..172..350L. doi:10.1103/PhysRev.172.350.
17Baker, George A. (1958). "Formulation of Quantum Mechanics Based on the Quasi-Probability Distribution Induced on Phase Space". Physical Review. 109 (6): 2198–2206. Bibcode:1958PhRv..109.2198B. doi:10.1103/PhysRev.109.2198.
